Heteropoly blue q7pmo12o42 ( q = c5h5nc16h33 ) has been designed and synthesized as reaction - controlled phase - transfer catalyst for catalytic epoxidation of cyclohexene and catalytic oxidation of benzalcoho with h2o2 as the oxidant 设计合成了第一个由磷钼杂多蓝作为反应控制相转移化剂的反应体系，用于对环己烯进行催化环氧化，苯甲醇进行催化氧化。
It was found that when the oxidation reaction was performed in toluene solvent , benzyl alcohol was oxidized to benzaldehyde without any overoxidation to benzoic acid ; on the contrary , in acetonitrile solvent , both benzaldehyde and benzoic acid were formed 发现在甲苯溶剂中进行氧化反应时，苯甲醇被氧化成苯甲醛而不会被深度氧化为苯甲酸；而在乙腈溶剂中，苯甲醛和苯甲酸均有生成。
Eighteen compounds in the oil were identified by g c / ms . they are : seven ketone compounds : 2 - undecanone , 6 , 10 - dimethy , 1 - cyclohexanol - l - butanone , 2 , 5 - hexanedione , 2 ( 4h ) - benzofuranone , 5 , 6 , 7 , 7 , a - tetrahydro - 4 , 4 , 7a - trimethyl , 3 - buten - 2 - one , 4 - ( 2 , 6 , 6 - trimethyl - 1 - cyclohex en - 1 - yl ) - , ( e ) , 6 - dodecanone , 3 - buten - 2 - one , 4 - ( 2 , 6 , 6 - trimethyl - 7 - oxabicycl o4 . 1 . 0hept - l - yl ) ; three alcoholic compounds : a - terpineol . benzyl alcoho 1 , phytol ; two alkyl and acyl amine components : undecane , tetradecane and hydrazinecarboxamide , n , n - diphenyl - , acetamidobenzene ; one ester , a idehyde , alkyne and acid : butanoic acid : 2 - propenyl ester , 1 - octadecyne , 1 - octadecyne , palmitic acid 三甲基一7一氧双环p ， l ， 0庚烷基什丁烯酮上；醇3种：苯甲醇、 a松油醇、 3 ， 7 ， 11 ， 15十六烯2醇1 ；烷2种：十一烷、十四烷；酚胺2种：姘基甲酚h苯胺、乙酞苯胺；酯、醛、炔、和酸备是1种：丁酸烯丙酯、十八碳醛、十八炔、十六碳酸。
Abstract : aim to synthesize a new prodrug , resveratrol trinicotinate . methods in presence of lithium and a catalytic amount of naphthalene , the reaction of p - methoxybenzyl trimethylsilyl ether and 3 , 5 - dimethoxylbenzaldehyde gave resveratrol after a series of translation . resveratrol trinicotinate was obtained by the reaction of resveratrol and nicotinoyl chloride hydrochloride . results a mutual prodrug resveratrol trinicotinate was designed and synthesized . conclusion a novel method for synthesis of resveratrol and resveratrol trinicotinate has been afforded . the e - isomer is selectivily obtained by dehydration of the compound 2 with khso4 文摘:目的合成一种前药白藜芦醇烟酸酯.方法在金属锂片和催化量的萘的存在下, 3 , 5 -二甲氧基苯甲醛与对甲氧基苯甲醇的三甲基硅醚反应经过一系列转变得到白藜芦醇,白藜芦醇与烟酰氯反应得到白藜芦醇烟酸酯.结果设计并合成了白藜芦醇烟酸酯.结论提供了一种合成白藜芦醇及白藜芦醇烟酸酯的方法,采用khso4脱水可选择性的得到反式产物
