The latest research progress in supramolecular fluorescence / phosphorescence sensors and switches used for metal cation recognition is summarized . two types of systems were reviewed , photo - induced electron transfer and monomer - excimer systems 本文总结了近年来用于金属离子识别的超分子荧光磷光传感器的研究工作进展，著重介绍了光诱导电子转移及单体激基缔合物体系在金属离子识别中的应用。
The latest research progress in supramolecular fluorescence / phosphorescence sensors and switches used for metal cation recognition is summarized . two types of systems were reviewed , photo - induced electron transfer and monomer - excimer systems 摘要本文总结了近年来用于金属离子识别的超分子荧光磷光传感器的研究工作进展，著重介绍了光诱导电子转移及单体激基缔合物体系在金属离子识别中的应用。
By evaperation of methol with a little pyridine existing , we abtained the supramolecular structure of resorcinarene binding molecular of water by hydrogen bond . this is a clathrate complexation which possessed a novel three dimention supramolecular structure 本文研究了间杯芳烃同吡啶分子于甲醇中形成的超分子体系，其单晶结构表明，间杯芳烃同吡啶分子通过氢键自组装形成了笼形包合物的超分子结构。
This article gives a review on the progress of the recognition and complexation between cucurbiturils as a noval macrocyclic host compound and metal ion , including the synthesis methods of supermolecular adducts , crystal structures , thermodynamics of binding and potential applications 摘要概述了新一代大环主体化合物南瓜尼与金属离子的识别及配合作用的研究进展，包括其超分子配合物的合成方法，晶体结构，键合的热力学性质及其应用前景。
In the crystal resorcinarene possessed the cone conformation , in array of head - tail columniation tube . actone molecular sited in the tube between two resorcinarenes . for the first time the one dimention nano - supramolecular - tube with association of neutral moleculer but not metal ion is reported 本文以间杯芳烃为超分子构造块，分析了它在丙酮、水存在下的单晶结构，发现，在多种弱相互作用力作用下，得到了新颖的纳米级一维超分子管道。
Electrochemlcal sensor was widely used in the analytical determination recentlythe studyofchemlcal modified electrode （ cme ） whlchact as electrochemlcal sensor was very plentiful the chemical modified carbon paste electrode （ cmcpe ） which was fabricated by mingling modifier with carbonpaste 叩 plledmore often the cpe has the characteristic ofeaslly modified ， wide using range ， fabricated easily3 innoculty ， long llte span etc because modified spedal substance cmcpe has spedal mnctlon ， it is studied more and more byelectfochemlcal worker now supermolecule chemistry ， the emerging and up to date cross su 刊 ect ， involves all su 刊 ects of chemistry biochemistry and material science etc inthatsupralllolecule c 卜 cthlstry chcffi1stfy offers an effective method for chemists to solve the long term puzzle of improving selectivity ， ithas gotten a great devebpment from it ’ s theory beingput forward we can expect the greatly wide application ofsupermolecule chemistry on cme but because the difficulty how to station it on the surface of ethetrode cannot be solved easily ， the application of supermolecule chemistry on cme was defined Cmcpe具有了一般碳糊电极的特点，同时又因为修饰了特定物质，使cmcpe具有了特定的功能，越来越受到电分析工作者青睐。而超分子化学是一个新兴的跨学科的交叉前沿领域，由于超分子化学解决了一直困扰化学工作者的选择性问题，因而从其理论提出以来，就得到了巨大的发展。可以预期超分子化学在化学修饰电极方面将有非常广阔的应用前景，但现在由于将超分子试剂修饰在电极这一环节上存在困难，所以现在超分子试剂在cpe上应用较少，在cmcpe中的应用更少。
2 . in order to deeply probe into the influence of crosslinked degree on er properties and expediently characterize the structure of the supramolecular complex , six hydrosoluble - cyclodextrin polymer / 3 - hydroxy - 2 - naphthoic acid er particles were synthesized . fluorescence analysis conformed that all the polymers can form 1 : 1 type supramolecular complex with the guest 为了进一步考察交联度对电流变效应的影响，并便于超分子配合物颗粒的结构表征，制备了6种不同交联度的水溶性-环糊精聚合物，以3 -羟基- 2 -萘甲酸为荧光探针探讨了不同交联度超分子配合物的组成、稳定性及荧光性质。
The supramolecular complexes of - cyclodextrin cross - linking polymer / l - ( 2 - pyridlazo ) - 2 - naphthol er particles were synthesized by self - assembly . the structure of the supramolecular complex was characterized by the fluorescence analysis , ir spectrometry and chem3d simulation , respectively . the results confirmed that the naphthalene ring of the guest is included in the cavity of - cyclodextrin cross - linking polymer 用荧光分析、 ir 、 xrd及计算机模拟手段对颗粒结构进行了表征，发现客体分子中极性较小的萘环进入环糊精的疏水内腔，形成了不溶性-环糊精聚合物超分子配合物。
It was found that the electrorheological properties , the dielectric properties , the temperature dependence and the sedimentation stability of the typical supramolecular complex er fluids were much higher than that of pure - cyclodextrin polymer . furthermore , the er behaviors can be regularly affected by the cross - linked degree of the supramolecular complex . the results indicated that the suitable range of cross - linked degree was 4 - 8 对比测试超分子配合物及主体材料配制的电流变液，发现超分子配合物电流变液的介电性能、流变学性能、温度效应以及抗沉降性能等均有明显提高，并发现聚合物的交联度对电流变效应影响较大，可以作为调节主体材料结构与性能的特征量。
The results showed that the forming constant and the fluorescence relative intensity were increased with the increase of cross - linked degree , and also , a well straight line of i vs . cross - linked degree was obtained ( where i = i - i0 , i is the fluorescence relative intensity of guest in the presence of different - cyclodextrin polymer and i0 is that of guest in aqueous solution ) . the electrorheological properties of suspensions of these particles in silicon oil have been investigated under dc electric field , which exhibited a significant er behavior 结果表明，超分子配合物中主-客体配比均为1 ： 1 ，其生成常数和相对荧光强度均随交联度的增长呈上升趋势，且相对荧光强度的增量与对应的交联度存在良好的线性关系。电流变液性能测试发现， 6种超分子配合物电流变液在3kv mm直流电场作用下，其屈服应力达3 . 38 5 . 98kpa ，与对应聚合物相比，平均增加了47 . 6 。
